The fourth season of Chuck was announced on May 13, 2010. Having initially ordered 13 episodes, NBC ordered an additional 11 on October 19, 2010 for a total of 24 episodes. Throughout the season, Chuck faced individual villains: Alexei Volkoff, head of Volkoff Industries, and Volkoff’s daughter, Vivian McArthur.
Josh Schwartz and Chris Fedak expressed a desire to continue the series past the fourth season as early as March 2011, when it was announced that the season finale would be titled “Chuck Versus the Cliffhanger”. The episode, as the title suggests, had a cliffhanger ending leading into the fifth and final season, which was ordered on May 13, 2011.
4 - 1Chuck Versus the Anniversary Sep. 20, 2010
4 - 2Chuck Versus the Suitcase Sep. 27, 2010
4 - 3Chuck Versus the Cubic Z Oct. 04, 2010
4 - 4Chuck Versus the Coup d'Etat Oct. 11, 2010
4 - 5Chuck Versus the Couch Lock Oct. 18, 2010
4 - 6Chuck Versus the Aisle of Terror Oct. 25, 2010
4 - 7Chuck Versus the First Fight Nov. 01, 2010
4 - 8Chuck Versus the Fear of Death Nov. 15, 2010
4 - 9Chuck Versus Phase Three Nov. 22, 2010
4 - 10Chuck Versus the Leftovers Nov. 29, 2010
4 - 11Chuck Versus the Balcony Jan. 17, 2011
4 - 12Chuck Versus the Gobbler Jan. 24, 2011
4 - 13Chuck Versus the Push Mix Jan. 31, 2011
4 - 14Chuck Versus the Seduction Impossible Feb. 07, 2011
4 - 15Chuck Versus the Cat Squad Feb. 14, 2011
4 - 16Chuck Versus the Masquerade Feb. 21, 2011
4 - 17Chuck Versus The First Bank Of Evil Feb. 28, 2011
4 - 18Chuck Versus the A-Team Mar. 14, 2011
4 - 19Chuck Versus the Muuurder Mar. 21, 2011
4 - 20Chuck Versus the Family Volkoff Apr. 11, 2011
4 - 21Chuck Versus the Wedding Planner Apr. 18, 2011
4 - 22Chuck Versus Agent X May. 02, 2011
4 - 23Chuck Versus the Last Details May. 09, 2011
4 - 24Chuck Versus the Cliffhanger May. 16, 2011
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